Crystal structure of dimethylgold(III) 8-hydroxyquinolinate and 8-mercaptoquinolinate

被引：6
|
作者：
Bessonov, A. A. [1 ]
Baidina, I. A. [1 ]
Morozova, N. B. [1 ]
Kuratieva, N. V. [1 ]
Gelfond, N. V. [1 ]
Igumenov, I. K. [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 49卷 / 01期
关键词：
dimethylgold(III) 8-hydroxyquinolate; 8-mercaptoquinolate; crystal structure;
D O I：
10.1007/s10947-008-0010-y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A crystal-chemical study of dimethylgold(III) complexes with 8-hydroxyquinoline (CH3)(2)Au(OR) and 8-mercaptoquinoline (CH3)(2)Au(SR) (R = C9H6N) was performed. Crystal data for (CH3)(2)Au(OR): a = 8.7133(17) angstrom, b = 27.875(6) angstrom, c = 8.6688(17) angstrom, beta = 102.76(3)degrees, Z = 8, rho(calc) = 2.401 g/cm(3), space group P2(1)/c, R = 0.0909; for (CH3)(2)Au(SR): a = 3.5401(7 angstrom, b = 15.689(3) angstrom, c = 19.910(4) angstrom, beta = 99.81(3)degrees, Z = 4, rho(calc) = 2.361 g/cm(3), space group P2(1)/c, R = 0.0712. Both structures are molecular and involve neutral (CH3)(2)Au(L) molecules, L = C9H6NO or C9H6NS. In the structures, the molecules are arranged in stacks joined by van der Waals interactions. The average Au...Au intrastack distances are 3.57 angstrom and 4.34 angstrom for (CH3)(2)Au(OR) and 3.5 angstrom for (CH3)(2)Au(SR).
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页码：64 / 68
页数：5
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