Micro-PIXE analysis of an ancient Egyptian papyrus:: Identification of pigments used for the "Book of the Dead"

This paper reports a study of colours and inks of an ancient Egyptian papyrus using an external proton microprobe in PIXE mode. Representing the Book of the Dead, this papyrus is dated from the 19th dynasty, New Kingdom (c. 1295-1186 BC). Elemental maps were obtained by moving the papyrus under a fixed focused external beam using a motorised support. The maps were compared to photographic pictures taken in visible light. Inks used in the hieroglyph text appeared to be based on carbon (black) and iron oxide (red). Coloured drawings illustrating the text showed a wider palette: hematite, ochre, orpiment, Egyptian blue, verdigris. Most intriguing was the observation in several parts of the drawing of a whitish pigment containing strontium. Deposits of strontium-rich minerals (e.g. strontianite, celestite) have been identified in Egypt. The exact nature and the archaeological implications of this pigment have still to be determined. Finally, fine powder and coarse grains of arsenic oxide were observed, probably remaining from an early preservation treatment against insect attacks after excavation. (C) 2001 Published by Elsevier Science B.V.