A robust hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex: Synthesis and its catalytic application towards Suzuki-Miyaura couplings in aqueous solvents

被引：82
|
作者：
Tu, Tao [1 ]
Feng, Xike [1 ]
Wang, Zhixun [1 ]
Liu, Xiyu [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 44期
基金：
美国国家科学基金会;
关键词：
N-HETEROCYCLIC CARBENES; COORDINATION; PRECATALYSTS; AGGREGATION; CHEMISTRY; EFFICIENT; WATER; GELATORS;
D O I：
10.1039/c0dt01083a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex (3) acted as a highly efficient robust recyclable molecular catalyst towards Suzuki-Miyaura coupling reactions in aqueous media and tolerated various functional groups (even heterocycles) with extremely low catalyst loading.
引用
收藏
页码：10598 / 10600
页数：3
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