Applications of Tandem Diels-Alder/Sigmatropic Rearrangement Reactions to Natural Product Synthesis

被引：7
|
作者：
Neier, Reinhard [1 ]
Banach, Ewa [1 ]
机构：
[1] Univ Neuchatel, Fac Sci, Dept Chem, CH-2000 Neuchatel, Switzerland
来源：
CURRENT ORGANIC CHEMISTRY | 2016年 / 20卷 / 22期
基金：
瑞士国家科学基金会;
关键词：
Diels-Alder; cycloaddition; sigmatropic rearrangements; tandem cascade; tactical combination; retrosynthesis; ENDIANDRIC ACID CASCADE; CLAISEN/DIELS-ALDER/CLAISEN REARRANGEMENT; STEREOCONTROLLED TOTAL-SYNTHESIS; SYNTHESIS-INFORMED DESIGN; MASKED O-BENZOQUINONES; ORGANIC-SYNTHESIS; ALDER REACTION; LEWIS-ACID; STEREOSELECTIVE-SYNTHESIS; COPE REARRANGEMENT;
D O I：
10.2174/1385272820666160331234505
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this non-comprehensive review a selection of tandem processes combining sigmatropic rearrangement with Diels-Alder reactions is presented. The synthetic utility of these two transformations is indisputable as they can lead to complex natural products in an efficient and selective way. Most of the examples presented here have been chosen in view of their application to natural products synthesis. The emphasis of the discussion is put on the illustration of new strategic disconnections becoming accessible thanks to tandem processes.
引用
收藏
页码：2326 / 2357
页数：32
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