Distinction of ortho- and para-xylene by femtosecond-laser mass spectrometry

被引:11
|
作者
Urbasch, Gunter [1 ]
Breunig, Hans Georg [1 ]
Weitzel, Karl-Michael [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
关键词
analytics; femtochemistry; isomers; linear chirp; mass spectrometry;
D O I
10.1002/cphc.200700498
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Isomer distinction: Using femtosecond-laser mass spectrometry structural isomers of xylene, that exhibit almost identical conventional electron impact mass spectra, can be distinguished. For femtosecond-pulse ionization the ion yields of the atomic fragments C+ and C2+ carry the memory of the structural identity of their parent molecules. (Graph Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2185 / 2188
页数:4
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