Tuning the reactivity of oxide surfaces by charge-accepting adsorbates

被引：52
|
作者：
Wang, Yuemin
Xia, Xinyu
Urban, Alexander
Qiu, Hengshan
Strunk, Jennifer
Meyer, Bernd
Muhler, Martin [1 ]
Woell, Christof
机构：
[1] Ruhr Univ Bochum, Lehrstuhl Tech Chem, D-44780 Bochum, Germany
[2] Ruhr Univ Bochum, Lehrstuhl Physkal Chem 1, D-44780 Bochum, Germany
[3] Ruhr Univ Bochum, Lehrstuhl Tech Chem, D-44780 Bochum, Germany
[4] Ruhr Univ Bochum, Lehrstuhl Theoret Chem, D-44780 Bochum, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 38期
关键词：
ab initio calculations; heterogeneous catalysis; microcalorimetry; vibrational spectroscopy; zinc oxide;
D O I：
10.1002/anie.200702815
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bridging the materials and pressure gaps : The adsorption of CO on ZnO surfaces becomes much stronger in the presence of preadsorbed CO2 (see picture; O red, Zn gray, C green). The increased strength of the interaction between CO and polycrystalline ZnO powder originates from the formation of tridentate carbonate species on the mixed-terminated (1010) surfaces, which increase the Lewis acidity of neighboring Zn2+ cations. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH &. Co. KGaA.
引用
收藏
页码：7315 / 7318
页数：4
相关论文
共 50 条
  • [1] Space-charge transfer at intrinsic defects and at (organic) adsorbates at metal-oxide surfaces
    Scheffler, Matthias
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [2] DYNAMIC BEHAVIOR OF ADSORBATES ON THORIUM OXIDE SURFACES
    JEZIOROW.H
    KNOZINGE.H
    BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1972, 76 (10): : 1118 - &
  • [3] ELECTRONIC AND GEOMETRIC STRUCTURE OF ADSORBATES ON OXIDE SURFACES
    CAPPUS, D
    MENGES, M
    XU, C
    EHRLICH, D
    DILLMANN, B
    VENTRICE, CA
    LIBUDA, J
    BAUMER, M
    WOHLRAB, S
    WINKELMANN, F
    KUHLENBECK, H
    FREUND, HJ
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1994, 68 : 347 - 355
  • [4] THE REACTIVITY OF OXIDE SURFACES
    WINTER, ERS
    ADVANCES IN CATALYSIS, 1958, 10 : 196 - 241
  • [5] Photoreaction dynamics of molecular adsorbates on semiconductor and oxide surfaces
    Osgood, Richard
    CHEMICAL REVIEWS, 2006, 106 (10) : 4379 - 4401
  • [6] The influence of oxide and adsorbates on the nanomechanical response of silicon surfaces
    Asif, SAS
    Wahl, KJ
    Colton, RJ
    JOURNAL OF MATERIALS RESEARCH, 2000, 15 (02) : 546 - 553
  • [7] The influence of oxide and adsorbates on the nanomechanical response of silicon surfaces
    Syed Asif S.A.
    Wahl K.J.
    Colton R.J.
    Journal of Materials Research, 2000, 15 (2) : 546 - 553
  • [8] Tuning Electron-Accepting Properties of Phthalocyanines for Charge Transfer Processes
    Bednarik, Stefan
    Demuth, Jiri
    Kernal, Jakub
    Miletin, Miroslav
    Zimcik, Petr
    Novakova, Veronika
    INORGANIC CHEMISTRY, 2024, 63 (19) : 8799 - 8806
  • [9] A review of quantitative structural determinations of adsorbates on metal oxide surfaces
    Daniels, BG
    Lindsay, R
    Thornton, G
    SURFACE REVIEW AND LETTERS, 2001, 8 (1-2) : 95 - 120
  • [10] Angle resolved autoionization spectra of adsorbates on metal oxide surfaces
    J Electron Spectrosc Relat Phenom, (37):
12345