Electron capture induced dissociation of dipeptide dications: where does the charge go?

被引:10
|
作者
Jensen, Camilla Skinnerup [1 ]
Wyer, Jean Ann [1 ]
Nielsen, Steen Brondsted [1 ]
机构
[1] Aarhus Univ, Dept Phys & Astron, DK-8000 Aarhus C, Denmark
关键词
PEPTIDE CATION-RADICALS; N-C-ALPHA; GAS-PHASE; NONERGODIC PROCESS; PROTEIN CATIONS; IONS; MECHANISM; KINETICS; AMIDE;
D O I
10.1039/c0cp00592d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Charge partitioning after electron capture induced dissociation of dipeptide dications is determined by proton mobility in the evanescent ion-molecule complex as the remaining proton has enough time to choose the fragment with the highest proton affinity.
引用
收藏
页码:12961 / 12963
页数:3
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