Ultrafiltration PVDF hollow fibre membranes with interconnected bicontinuous structures produced via a single-step phase inversion technique

被引：67
|
作者：
Abed, M. R. Moghareh [1 ]
Kumbharkar, S. C. [1 ]
Groth, Andrew M. [2 ]
Li, K. [1 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2AZ, England
[2] Siemens Water Technol, Memcor Prod, S Windsor, NSW 2756, Australia
来源：
JOURNAL OF MEMBRANE SCIENCE | 2012年 / 407卷
基金：
英国工程与自然科学研究理事会;
关键词：
Poly(vinylidene fluoride); Triethyl phosphate; Hollow fibre membrane; Ultrafiltration; Wastewater treatment; Additive; Polyethylene glycol; POLY(VINYLIDENE FLUORIDE) MEMBRANES; IMMERSION PRECIPITATION; FINE-STRUCTURE; MORPHOLOGY; PERFORMANCE; PERMEATION;
D O I：
10.1016/j.memsci.2012.03.029
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
PVDF hollow fibre membranes with interconnected bicontinuous structures were produced from PVDF/TEP solutions using a single-step phase inversion method. Hollow fibres with excellent mechanical strength and very dense inner and outer skin layers were obtained using a PVDF/TEP solution. Due to the hydrophobic nature of PVDF and formation of the dense skin layers, the produced membranes were not suitable for water and wastewater applications. In order to improve the water flux, two different molecular weight PEGs were employed to eliminate the dense skin and as pore-forming agent additives. A wide range of ultrafiltration hollow fibre membranes, suitable for water and wastewater treatments and similar to modified industrial PVDF ultrafiltration membranes were produced by using PVDF/TEP/PEG dope solutions with the adjusted spinning parameters. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：145 / 154
页数：10
相关论文
共 12 条
  • [1] PVDF hollow fibre membranes with interconnected bicontinuous structures produced via immersion precipitation technique
    Abed, M. R. Moghareh
    Kumbharkar, S. C.
    Groth, A. M.
    Li, K.
    EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 571 - 572
  • [2] Chemistry in spinning solutions: Hydrophilic modification of PVDF hollow fibre membranes during phase inversion
    Hashim, N. A.
    Lie, K.
    EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 351 - 354
  • [3] Preparation of PVDF hollow fiber ultrafiltration membrane via phase inversion/chemical treatment method
    Huang, Dan-xi
    Wang, Lei
    Meng, Xiao-rong
    Wang, Xu-dong
    Zhao, Liang
    DESALINATION AND WATER TREATMENT, 2014, 52 (25-27) : 5076 - 5083
  • [4] Characterization and preparation of poly(vinylidene fluoride) (PVDF) microporous membranes with interconnected bicontinuous structures via non-solvent induced phase separation (NIPS)
    Zhang, Ping-Yun
    Yang, Hu
    Xu, Zhen-Liang
    Wei, Yong-Ming
    Guo, Jun-Lian
    Chen, Dong-Gen
    JOURNAL OF POLYMER RESEARCH, 2013, 20 (02)
  • [5] Characterization and preparation of poly(vinylidene fluoride) (PVDF) microporous membranes with interconnected bicontinuous structures via non-solvent induced phase separation (NIPS)
    Ping-Yun Zhang
    Hu Yang
    Zhen-Liang Xu
    Yong-Ming Wei
    Jun-Lian Guo
    Dong-Gen Chen
    Journal of Polymer Research, 2013, 20
  • [6] Dual PVP roles for preparing PVDF hollow fiber membranes with bicontinuous structures via the complex thermally induced phase separation (c-TIPS)
    Hou, Chunguang
    Pang, Zhiguang
    Xie, Songchen
    Yang, Ziyun
    Wong, Ngie Hing
    Sunarso, Jaka
    Peng, Yuelian
    SEPARATION AND PURIFICATION TECHNOLOGY, 2024, 332
  • [7] Mitigating the Hydraulic Compression of Nanofiltration Hollow Fiber Membranes through a Single-Step Direct Spinning Technique
    Ong, Yee Kang
    Chung, Tai-Shung
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2014, 48 (23) : 13933 - 13940
  • [8] Synthesis and Properties of Proton Exchange Membranes via Single-Step Grafting PSBMA onto PVDF Modified by TMAH
    Zhang Jia-Han
    Guo Gui-Bao
    An Sheng-Li
    Hao Fan
    Zhang Dong
    Yan Kai-Bo
    ACTA PHYSICO-CHIMICA SINICA, 2015, 31 (10) : 1905 - 1913
  • [9] Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate (LiClO4) as an additive
    Yeow, ML
    Liu, YT
    Li, K
    JOURNAL OF MEMBRANE SCIENCE, 2005, 258 (1-2) : 16 - 22
  • [10] Single-Step Fabrication Using a Phase Inversion Method of Poly(vinylidene fluoride) (PVDF) Activated Carbon Air Cathodes for Microbial Fuel Cells
    Yang, Wulin
    He, Weihua
    Zhang, Fang
    Hickner, Michael A.
    Logan, Bruce E.
    ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS, 2014, 1 (10): : 416 - 420
12