Advances in Chemocatalytic Asymmetric Baeyer-Villiger Oxidations

被引：28
|
作者：
Liu, Chao [1 ]
Wen, Kai-Ge [1 ]
Zeng, Xing-Ping [1 ]
Peng, Yi-Yuan [1 ]
机构：
[1] Jiangxi Normal Univ, Key Lab Small Funct Organ Mol, Minist Educ, Nanchang 330022, Jiangxi, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 05期
基金：
中国国家自然科学基金;
关键词：
chiral lactones; chiral metal catalysis; chiral organocatalysis; cyclic ketones; enantioselective Baeyer-Villiger oxidation; HYDROGEN-PEROXIDE; 3-SUBSTITUTED CYCLOBUTANONES; PROCHIRAL CYCLOBUTANONES; KINETIC RESOLUTION; CYCLIC-KETONES; ACID; CATALYSTS; H2O2; DESYMMETRIZATION; PROSTAGLANDIN;
D O I：
10.1002/adsc.201901178
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Baeyer-Villiger oxidations, first reported by Adolf von Baeyer and Victor Villiger 120 years ago, are highly efficient methodologies for the syntheses of esters or lactones from ketones. The asymmetric Baeyer-Villiger oxidations using racemic, prochiral and meso-cyclic ketones allow a rapid access to chiral lactones, which are valuable intermediates for the subsequent synthesis of bioactive compounds and natural products. The current review provides a summary on the advances in chemocatalytic enantioselective B-V oxidations. The latest achievements in this field and their applications are presented.
引用
收藏
页码：1015 / 1031
页数：17
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