NA6(H2O)20(V10O28)•4H2O, a novel polyvanadate(V) with a three-dimensional framework

被引：5
|
作者：
Guo, Hong-Xu [1 ]
Yao, Zhong-Liang
机构：
[1] Zhangzhou Normal Univ, Dept Chem & Environm Sci, Fujian 363000, Peoples R China
[2] Fujian Normal Univ, Fuqing Branch, Dept Biol & Chem Engn, Fujian 350300, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷
关键词：
D O I：
10.1107/S0108270107025395
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The novel title polyvanadate(V), poly[[octa-mu-aqua-dodeca-aqua-mu(4)-octacosaoxidodecavanadato-hexasodium] tetrahydrate], [Na-6(H2O)(20)(V10O28)center dot 4H(2)O](n), contains [V10O28](6-) anions which lie about inversion centres and have approximate 2/m symmetry and which are linked to [Na-3(H2O)(10)](3+) cations through two terminal and two mu(2)-bridging O atoms. The structure contains three inequivalent Na+ cations, two of which form [Na-2(H2O)(8)](n) chains, which are linked via NaO6 octahedra involving the third Na+ ion, thus forming a three-dimensional framework.
引用
收藏
页码：I51 / I53
页数：3
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