Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins

被引：48
|
作者：
Maeda, Chihiro [1 ]
Ogawa, Kanae [1 ]
Sadanaga, Kosuke [1 ]
Takaishi, Kazuto [1 ]
Ema, Tadashi [1 ]
机构：
[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Appl Chem, Okayama 7008530, Japan
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 08期
关键词：
CIRCULARLY-POLARIZED LUMINESCENCE; CARBON-DIOXIDE FIXATION; CYCLIC CARBONATES; ASYMMETRIC EPOXIDATION; METALLOPORPHYRIN CATALYSTS; ENANTIOSELECTIVE SYNTHESIS; PHOTOPHYSICAL PROPERTIES; OPTICAL RESOLUTION; EFFICIENT CATALYST; RECENT PROGRESS;
D O I：
10.1039/c8cc09114e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Doubly (R)-binaphthyl-strapped porphyrins with methylene chains were synthesized. The CD spectra showed the positive Cotton effect around the Soret bands, and several porphyrins showed CPL. In addition, we found that the chiral porphyrins were applicable to kinetic resolution of epoxide with CO2.
引用
收藏
页码：1064 / 1067
页数：4
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