Nowadays, two exciters vibration system played an indispensable role in a majority of machinery and devices, such as vibratory feeder, vibrating screen, vibration conveyer, vibrating crusher, and so on. The stability of the system and the synchronous characteristics of two exciters are affected by material motion. However, those effects of material on two exciters vibration system were studied very little. Based on the special background, a mechanical model that two exciters vibration system considering material motion is proposed. Firstly, the system's dynamic equations are solved by using Lagrange principle and Newton's second law. Then, the motion stability of the system when material with different mass move on the vibrating body is analyzed by Poincare' mapping and numerical simulation methods, and the motion forms of the material are also studied. Meanwhile, the frequency responses of the vibrating body are analyzed. Finally, the influence of material on the phase difference of the two exciters is revealed. It can be concluded that with the mass ratio of the material to the vibrating body increasing, the system's motion evolves from stable periodic motion to chaotic state, the synchronization ability of two exciters decline, and the unpredictability of abrupt change about the phase difference increases. Further, the uncertainties of both the abrupt change of phase difference and the collision location affect each other and eventually lead to the instability of the system.