New preparations of lignin polymer models under conditions that approximate cell wall lignification .2. Structural characterization of the models by thioacidolysis

被引：74

作者：

Terashima, N ^{[1
]}

Atalla, RH ^{[1
]}

Ralph, SA ^{[1
]}

Landucci, LL ^{[1
]}

Lapierre, C ^{[1
]}

Monties, B ^{[1
]}

机构：

[1] INST NATL AGRON PARIS GRIGNON, INRA, CHIM BIOL LAB, F-78850 THIVERVAL GRIGNON, FRANCE

来源：

HOLZFORSCHUNG | 1996年 / 50卷 / 01期

基金：

美国能源部;

关键词：

lignin polymer model; dehydrogenation polymer of monolignol (DHP); coniferin; monolignol glucoside; coniferyl alcohol; thioacidolysis;

D O I：

10.1515/hfsg.1996.50.1.9

中图分类号：

S7 [林业];

学科分类号：

0829 ; 0907 ;

摘要：

The structures of novel lignin polymer models prepared from coniferin or coniferyl alcohol under conditions that approximate cell wall lignification were characterized by thioacidolysis. The linkage-type analysis by thioacidolysis indicates that the structure of these polylignols approximated that of native lignin more closely than did the structure of polylignols prepared by the conventional method from coniferyl alcohol. Among various possible factors affecting the structure of polylignols during polymerization under the present experimental conditions, the important ones appears to be: pH of the medium in which dehydrogenative polymerization of coniferyl alcohol takes place; relative concentrations of monomer and oligomer radicals; and the carbohydrate matrix in which polymerization occurs.

引用

页码：9 / 14

页数：6

共 31 条

[1] NEW PREPARATIONS OF LIGNIN POLYMER MODELS UNDER CONDITIONS THAT APPROXIMATE CELL-WALL LIGNIFICATION .1. SYNTHESIS OF NOVEL LIGNIN POLYMER MODELS AND THEIR STRUCTURAL CHARACTERIZATION BY C-13 NMR
TERASHIMA, N
ATALLA, RH
RALPH, SA
LANDUCCI, LL
LAPIERRE, C
MONTIES, B
HOLZFORSCHUNG, 1995, 49 (06) : 521 - 527
[2] New preparations of lignin polymer models under conditions that approximate cell well lignification. I: Synthesis of novel lignin polymer models and their structural characterization by 13C NMR
USDA forest serv., forest product lab., Madison WI 53705-2398
Holzforschung, 6 (521-527):
[3] A NEW PREPARATION OF POLYLIGNOLS UNDER CONDITIONS WHICH APPROXIMATE CELL-WALL LIGNIFICATION
TERASHIMA, N
LANDUCCI, LL
RALPH, SA
ATALLA, RH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 65 - CELL
[4] INSOLUBLE LIGNIN MODELS .2. PREPARATION, CHARACTERIZATION, AND REACTIONS OF A POLYMER-BOUND BETA-ARYL ETHER LIGNIN MODEL
APFELD, PB
BOVEE, LF
BARKHAU, RA
DIMMEL, DR
JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 1988, 8 (04) : 483 - 504
[5] KINETIC-MODELS FOR PEROXIDE BLEACHING UNDER ALKALINE CONDITIONS .2. EQUILIBRIUM-MODELS
WRIGHT, PJ
GINTING, YA
ABBOT, J
JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 1992, 12 (01) : 111 - 134
[6] New structural models of the 'building-base' system under the conditions of loess sagging soils
Mezherovskij, V.A., 1600,
[7] Using biomimetic cell wall models to identify new plant lignin bioengineering targets for improving forage and biomass utilization
Grabber, John H.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[8] Polymer solutions under elongational flow: 2. An evaluation of models of polymer dynamics for transient and stagnation point flows
Dept of Chemistry, Federal Inst of Technology, EPFC-DC-IGC-I, Lausanne CH-1015, Switzerland
Polymer, 19 (4271-4281):
[9] Polymer solutions under elongational flow .2. An evaluation of models of polymer dynamics for transient and stagnation point flows
Hunkeler, D
Nguyen, TQ
Kausch, HH
POLYMER, 1996, 37 (19) : 4271 - 4281
[10] Anthraquinone polymer catalysts for alkaline delignification of lignocellulosic matter. Part 2. Action in soda pulping conditions on softwood and phenolic β-O-4 lignin models
Cazeils, Emmanuel
Megiatto, Jackson D., Jr.
Gardrat, Christian
Pichavant, Frederique
Grelier, Stephane
Castellan, Alain
HOLZFORSCHUNG, 2012, 66 (06) : 691 - 697

← 1 2 3 4 →