Supercritical carbon dioxide-soluble fluorus vic-dioxime Ligands and their NiII complexes:: Synthesis, characterization and solubility properties

被引：3
|
作者：
Guzel, B. [1 ]
Avsar, G. [1 ]
Cinkir, H. F. [1 ]
机构：
[1] Cukurova Univ, Fac Sci & Letters, Dept Chem, TR-01330 Adana, Turkey
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2007年 / 37卷 / 10期
关键词：
dioxime; chelate; metal extraction; supercritical carbon dioxide;
D O I：
10.1080/15533170701740982
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New supercritical carbon dioxide s oluble ligands, N,N'-bis(4-trifluoromethyl phenylamino)glyoxime, N,N'-bis(3-triftuoromethylphenylamino)glyoxime, NN'-bis(3,5-ditrifluoromethyl phenylamino)glyoxime and their Ni-II complexes have been prepared and characterized by spectroscopic methods and elemental analysis. The solubility of the synthesized ligands and their Ni-II complexes were measured at 343.15 K and 172.4 bar in supercritical carbon dioxide.
引用
收藏
页码：801 / 804
页数：4
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