Microwave-assisted synthesis and electrochemical capacitance of polyaniline/multi-wall carbon nanotubes composite

被引：145
|
作者：
Mi, Hongyu [2 ,3 ]
Zhang, Xiaogang [1 ]
An, Shuying [2 ]
Ye, Xiangguo [2 ]
Yang, Sudong [2 ]
机构：
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R China
[2] Xinjiang Univ, Inst Appl Chem, Urumqi 830046, Peoples R China
[3] Xi An Jiao Tong Univ, Coll Sci, Xian 710049, Peoples R China
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 12期
基金：
中国国家自然科学基金;
关键词：
polyaniline; multi-wall carbon nanotubes; microwave-assisted; supercapacitor;
D O I：
10.1016/j.elecom.2007.10.013
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Polyaniline/multi-wall carbon nanotubes composite (PANI/MWNTs) was rapidly synthesized by microwave-assisted polymerization. Transmission electron microscope (TEM) image revealed that this composite was a core-shell structure with PANI layers (50-70 nm). Electrochemical behavior of the composite was evaluated by cyclic voltammetry (CV) and galvanostatic charge-discharge tests with a two-electrode system. An enhanced specific capacitance of 322 F/g with a specific energy density of 22 W h/kg was about 12 times that of MWNTs. This composite also exhibited a good rate capability, retaining up to 87% of initial capacity at a current density of 5 mA/cm(2). (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：2859 / 2862
页数：4
相关论文
共 50 条
  • [1] Multi-wall carbon nanotubes coated with polyaniline
    Konyushenko, Elena N.
    Stejskal, Jaroslav
    Trchova, Miroslava
    Hradil, Jiri
    Kovarova, Jana
    Prokes, Jan
    Cieslar, Miroslav
    Hwang, Jeong-Yuan
    Chen, Kuei-Hsien
    Sapurina, Irina
    POLYMER, 2006, 47 (16) : 5715 - 5723
  • [2] Conducting polyaniline/multi-wall carbon nanotubes composite paints on low carbon steel for corrosion protection: electrochemical investigations
    Pravin P. Deshpande
    Sanket S. Vathare
    Shashikant T. Vagge
    Elena Tomšík
    Jaroslav Stejskal
    Chemical Papers, 2013, 67 : 1072 - 1078
  • [3] Conducting polyaniline/multi-wall carbon nanotubes composite paints on low carbon steel for corrosion protection: electrochemical investigations
    Deshpande, Pravin P.
    Vathare, Sanket S.
    Vagge, Shashikant T.
    Tomsik, Elena
    Stejskal, Jaroslav
    CHEMICAL PAPERS, 2013, 67 (08) : 1072 - 1078
  • [4] Electrochemical oxidation of multi-wall carbon nanotubes
    Moraitis, Giorgos
    Spitalsky, Zdeno
    Ravani, Fotini
    Siokou, Angeliki
    Galiotis, Costas
    CARBON, 2011, 49 (08) : 2702 - 2708
  • [5] Electrochemical fabrication and capacitance of composite films of carbon nanotubes and polyaniline
    Branzoi, Viorel
    Branzoi, Florina
    Pilan, Luisa
    SURFACE AND INTERFACE ANALYSIS, 2010, 42 (6-7) : 1266 - 1270
  • [6] Electrochemical fabrication and capacitance of composite films of carbon nanotubes and polyaniline
    Wu, MQ
    Snook, GA
    Gupta, V
    Shaffer, M
    Fray, DJ
    Chen, GZ
    JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (23) : 2297 - 2303
  • [7] Microwave purification of multi-wall carbon nanotubes in gas phase
    Zheng, Jia
    Bao, Rui
    Yi, Jian-hong
    Yang, Ping
    DIAMOND AND RELATED MATERIALS, 2016, 68 : 93 - 101
  • [8] Synthesis of multi-wall carbon nanotubes by simple pyrolysis
    Mahanundia, P.
    Vishwakarma, P. N.
    Nanda, K. K.
    Prasad, V.
    Barai, K.
    Mondal, A. K.
    Sarangi, S.
    Dey, G. K.
    Subramanyam, S. V.
    SOLID STATE COMMUNICATIONS, 2008, 145 (03) : 143 - 148
  • [9] The influence of pretreatment on multi-wall carbon nanotubes for electrochemical capacitors
    Geng Xin
    Li Feng
    Wang Da-wei
    Cheng Hui-ming
    NEW CARBON MATERIALS, 2013, 28 (02) : 146 - 150
  • [10] Electrochemical capacitance of MWCNT/polyaniline composite coatings grown in acidic MWCNT suspensions by microwave-assisted hydrothermal digestion
    Wu, Mengqiang
    Zhang, Liping
    Wang, Dongmei
    Gao, Jiahui
    Zhang, Shuren
    NANOTECHNOLOGY, 2007, 18 (38)
12345