Study on bioleaching of refractory gold ore (I) -: Mechanism on bioleaching of pyrite by Thiobacillus ferrooxidans

The variation of main parameters including ion concentration, pH value, potential and biomass was examined in bioleaching pyrite. The pH value of the solution decreased obviously. Most of T. ferrooxidans adhered to the surface of pyrite. The surface properties of pyrite and leached products were determined by SEM, EDS and XRD. Pyrite was corroded selectively by T. ferrooxidans and sulfur in pyrite was leached preferentially. The primary product for bioleaching pyrite was jarosite. Based on these results, it can be found that pyrite is oxidized mainly through the direct role of T. ferrooaxidans. A band model for bioleaching pyrite was built, by which the bioleaching process was explained theoretically. The model shows that the holes, which are injected into the valence band of pyrite through adhered T. ferrooxidans, result from dissolved oxygen in the solution.