Reaction of Re2(μ-O2CCH3)4Cl2 with bis(dicyclohexylphosphino)methane (dcpm):: Isolation of the mixed-valent complex O3ReReCl(η2-dcpm)2 containing an unsupported Re-Re bond

被引：13

作者：

Bera, JK ^{[1
]}

Fanwick, PE ^{[1
]}

Walton, RA ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 12期

关键词：

D O I：

10.1021/ic0100471

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Re2(μ-O2CCH3)4Cl2 with Cy2PCH2-PCy2 (dcpm) affords a separable mixture of trans-ReOCl(η2-dcpm)2 (1) and trans-Re2(μ-O2CCH3)2 Cl2(μ-dcpm)2 (2). Complex 1 is converted in the presence of O2 to the novel mixed-valent Re(VI)-Re(I) complex O3ReReCl(η2-dcpm)2 (3), which contains an unsupported Re-Re bond.

引用

页码：2914 / 2917

页数：4

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