{μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol-μ-nitrato-dinitratocopper(II)europium(III)

被引：4

作者：

Bao, Yan ^{[1
]}

Li, Guang-Ming ^{[1
]}

Yang, Fan ^{[1
]}

Yan, Peng-Fei ^{[1
]}

Chen, Peng ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

基金：

中国国家自然科学基金;

关键词：

MAGNETIC-PROPERTIES; COMPLEXES;

D O I：

10.1107/S1600536810039103

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title dinuclear salen- type complex, [CuEu(C22H24N2O4)(NO3)(3)(CH3OH)], the Cu-II ion is five-coordinated to two imine N atoms and two phenolate O atoms and one O from the bridging nitrate group. The Eu-III ion is ligated to three nitrate groups, four O atoms from the salen-type ligand and one methanol molecule, leading to a distorted tenfold coordination for the rare earth cation. One of the three nitrate anions is disordered over two positions in a 0.66 (5):0.34 (5) ratio.

引用

页码：M1379 / U410

页数：12

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