Self-assembled diamide nanotubes in organic solvents

被引：61
|
作者：
Díaz, N
Simon, FX
Schmutz, M
Rawiso, M
Decher, G
Jestin, J
Mésini, PJ
机构：
[1] Inst Charles Sadron, F-67083 Strasbourg, France
[2] CEA Saclay, Lab Leon Brilloin, F-91191 Gif Sur Yvette, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 21期
关键词：
colloids; materials science; nanotubes; self-assembly; supramolecular chemistry;
D O I：
10.1002/anie.200500536
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Hydrogen bonding and π-π interactions are the driving forces for the self-assembly of a diamide organogelator into nanotubes in organic solution. Freeze-fracture electron microscopy (see image) and small angle neutron scattering studies show the tubes have a diameter of (24.2 ± 0.3) nm with a wall thickness of (3.3 ± 0.4) nm and an aspect ratio of 1:50 or higher. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3260 / 3264
页数：5
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