Soft-donor dipicolinamide derivatives for selective actinide(iii)/lanthanide(iii) separation: the role of S- vs. O-donor sites

被引：39

作者：

Lehman-Andino, Ingrid ^{[1
,2
]}

Su, Jing ^{[3
]}

Papathanasiou, Konstantinos E. ^{[1
,2
]}

Eaton, Teresa M. ^{[4
,6
]}

Jian, Jiwen ^{[4
]}

Dan, David ^{[5
]}

Albrecht-Schmitt, Thomas E. ^{[5
]}

Dares, Christopher J. ^{[1
,2
]}

Batista, Enrique R. ^{[3
]}

Yang, Ping ^{[3
]}

Gibson, John K. ^{[4
]}

Kavallieratos, Konstantinos ^{[1
,2
]}

机构：

[1] Florida Int Univ, Dept Chem & Biochem, Miami, FL 33199 USA

[2] Florida Int Univ, Biomol Sci Inst, Miami, FL 33199 USA

[3] Los Alamos Natl Lab, Theoret Div, Los Alamos, NM 87545 USA

[4] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA

[5] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[6] Embry Riddle Aeronaut Univ, Prescott, AZ USA

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 17期

关键词：

ANION-PI INTERACTIONS; TRIVALENT ACTINIDES; AMERICIUM(III); EXTRACTION; LIGANDS; COMPLEXATION; LANTHANIDE; ACID; EUROPIUM(III); THIOAMIDE;

D O I：

10.1039/c8cc07683a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selectivity for An(III) vs. Ln(III) binding and extraction using dipicolinamide analogs containing the C=O vs. C=S groups was investigated in solution and the gas-phase, and by DFT calculations. The results show higher selectivity for complex formation and extraction for Am(III) vs. Eu(III) for the softer dithioamide vs. the diamide ligand, while in CH3CN the diamide binds more strongly than the thioamide to several Ln(III), forming 1:1 complexes.

引用

页码：2441 / 2444

页数：4

共 4 条

[1] Theoretical evaluation of mixed N-, O- donor based TMPhenDA ligand in selective complexation with actinide (III) ions over lanthanide (III) ions
Lipin, Raju
Ebenezer, Cheriyan
Solomon, Rajadurai Vijay
JOURNAL OF MOLECULAR LIQUIDS, 2021, 332 (332)
[2] Theoretical study on the bonding and extraction properties of actinide (III) ions by 3,3′-sulfonyldithiophene, an O-donor ligand based on tetrahedral bonding S center
Bai, Shan Qin
Liang, Yu Ting
Li, An Yong
STRUCTURAL CHEMISTRY, 2024, 35 (02) : 669 - 679
[3] Theoretical study on the bonding and extraction properties of actinide (III) ions by 3,3′-sulfonyldithiophene, an O-donor ligand based on tetrahedral bonding S center
Shan Qin Bai
Yu Ting Liang
An Yong Li
Structural Chemistry, 2024, 35 (2) : 669 - 679
[4] Coordination chemistry of N-aminopropyl pendant arm derivatives of mixed N/S-, and N/S/O-donor macrocycles, and construction of selective fluorimetric chemosensors for heavy metal ions
Aragoni, MC
Arca, M
Bencini, A
Blake, AJ
Caltagirone, C
Decortes, A
Demartin, F
Devillanova, FA
Faggi, E
Dolci, LS
Garau, A
Isaia, F
Lippolis, V
Prodi, L
Wilson, C
Valtancoli, B
Zaccheroni, N
DALTON TRANSACTIONS, 2005, (18) : 2994 - 3004

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