Surface Structure Build-Up and Three-Dimensional Topography of Polyurethane Powder Coatings

被引:4
|
作者
Pilch-Pitera, Barbara [1 ]
Stagraczynski, Ryszard [2 ]
机构
[1] Rzeszow Univ Technol, Fac Chem, Dept Polymer Sci, PL-35959 Rzeszow, Poland
[2] Rzeszow Univ Technol, Fac Math & Appl Phys, Dept Phys, PL-35959 Rzeszow, Poland
关键词
polyurethanes; coatings; surfaces; microstructure;
D O I
10.1002/app.32733
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Non- and polysilsesquioxane-containing polyurethane-based powder coating systems, crosslinked with allophanate bonds containing polyisocyartates were examined. The surface structure built-up of the powder coatings were investigated at different temperatures with a polarized optical microscopy (POM) using reflected light. The three-dimensional surface topography and the values of surface roughness were determined. The surface structure was correlated with the chemical structure of the coatings and macroscopic surface behavior: surface free energy and gloss. These experimental results lead to a better understanding of the development of surface topography and morphology and provide valuable information for the development of new polyurethane powder coating systems. (C) 2010 Wiley Periodicals, Inc. I Appl Polym Sci 118: 3586-3593, 2010
引用
收藏
页码:3586 / 3593
页数:8
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