Efficient synthesis of "Star-like" surfactants via "Click Chemistry" [3+2] copper (I)-catalyzed cycloaddition

被引：6

作者：

Neto, Virginie ^{[1
]}

Granet, Robert ^{[1
]}

Mackenzie, Grahame ^{[2
]}

Krausz, Pierre ^{[1
]}

机构：

[1] Univ Limoges, Fac Sci & Tech, Lab Chim Subst Nat, F-87060 Limoges, France

[2] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2008年 / 27卷 / 04期

关键词：

surfactant; carbohydrate; Click chemistry;

D O I：

10.1080/07328300802105365

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

We report an efficient synthesis of tetra- and hexa-substituted carbohydrate-coated compounds, which we have named star-like surfactants, starting from either alpha-methylglucose or myo-inositol as a central core. The synthesis explores a new approach to such multipolar compounds using [3+2] copper (I)-catalyzed cycloadditions to attach the respective building blocks.

引用

页码：231 / 237

页数：7

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