Rheology of stiff-chain polymer solutions

被引：6

作者：

Sato, Takahiro ^{[1
]}

机构：

[1] Osaka Univ, Dept Macromol Sci, 1-1 Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan

来源：

JOURNAL OF RHEOLOGY | 2022年 / 66卷 / 02期

关键词：

Stiff-chain polymer; Polymer solution; Intrinsic viscosity; Huggins coefficient; Zero shear viscosity; Mean-field Green function method; Rigid helical polysaccharide; Schizophyllan; Xanthan; CONCENTRATED ISOTROPIC SOLUTIONS; SCHIZOPHYLLUM-COMMUNE POLYSACCHARIDE; GREEN-FUNCTION FORMULATION; HELICAL WORMLIKE CHAINS; ROD-LIKE MACROMOLECULES; ZERO-SHEAR VISCOSITY; DILUTE-SOLUTION; VISCOELASTIC PROPERTIES; HYDRODYNAMIC PROPERTIES; SEMIFLEXIBLE POLYMERS;

D O I：

10.1122/8.0000397

中图分类号：

O3 [力学];

学科分类号：

08 ; 0801 ;

摘要：

Theoretical expressions for the intrinsic viscosity, the Huggins coefficient, zero-shear viscosity, and storage and loss moduli for stiff-chain polymer solutions are reviewed. Especially, the mean-field Green function method is explained in detail to consider the intermolecular collision effect on the rheological properties of concentrated stiff-chain polymer solutions, by applying the method to monodisperse and polydisperse straight cylinders and monodisperse fuzzy cylinder models. The theoretical expressions reviewed are compared with experimental results for aqueous solutions of two rigid helical polysaccharides, schizophyllan and xanthan. (c) 2022 The Society of Rheology.

引用

页码：399 / 414

页数：16

共 50 条

[1] Rheological properties of stiff-chain polymer solutions
Sato, T
NIHON REOROJI GAKKAISHI, 1999, 27 (04) : 205 - 212
[2] Extensional flow of stiff-chain polymer solutions in the semidilute regime
Romo-Uribe, Angel
JOURNAL OF APPLIED POLYMER SCIENCE, 2022, 139 (08)
[3] DYNAMIC LIGHT-SCATTERING STUDY OF SEMIDILUTE SOLUTIONS OF A STIFF-CHAIN POLYMER
RUSSO, PS
KARASZ, FE
LANGLEY, KH
JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (10): : 5312 - 5325
[4] Stiff-Chain Polyelectrolytes
Holm, C.
Rehahn, M.
Oppermann, W.
Ballauff, M.
Advances in Polymer Science, 2004, 166 : 1 - 27
[5] STIFF-CHAIN MACROMOLECULES
YAMAKAWA, H
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1984, 35 : 23 - 47
[6] Stiff-chain polyelectrolytes
Holm, C
Rehahn, M
Oppermann, W
Ballauff, M
POLYELECTROLYTES WITH DEFINED MOLECULAR ARCHITECTURE II, 2004, 166 : 1 - 27
[7] Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules
Vasilevskaya, V. V.
Markov, V. A.
ten Brinke, G.
Khokhlov, A. R.
MACROMOLECULES, 2008, 41 (20) : 7722 - 7728
[8] Dynamics of stiff-chain polymers in multicomponent solutions: Modification of the hole theory
Fujiyama, T
Sato, T
Teramoto, A
ACTA POLYMERICA, 1995, 46 (06) : 445 - 452
[9] LOCALIZATION OF THE LIQUID-CRYSTALLINE STATE IN SOLUTIONS OF A STIFF-CHAIN POLYAMIDE
FORSTER, G
REUSSNER, J
JANKOWSKI, A
KUSCHEL, F
WAGNER, R
CRYSTAL RESEARCH AND TECHNOLOGY, 1989, 24 (11) : K201 - K206
[10] Osmotic coefficient calculations for dilute solutions of short stiff-chain polyelectrolytes
Antypov, Dmytro
Holm, Christian
MACROMOLECULES, 2007, 40 (03) : 731 - 738

← 1 2 3 4 5 →