The first example of the reactions of cyclopropenes with N-acyliminium cations generated from hydroxylactams

被引：12

作者：

Larina, Anna G. ^{[1
]}

Nosova, Vlada E. ^{[1
]}

Filatov, Alexander S. ^{[1
]}

Molchanov, Alexander P. ^{[1
]}

Starova, Galina L. ^{[1
]}

Zolotarev, Andrey A. ^{[1
]}

Boitsov, Vitaly M. ^{[2
,3
]}

Stepakov, Alexander V. ^{[1
,4
]}

机构：

[1] St Petersburg State Univ, Univ Emb 7-9, St Petersburg 199034, Russia

[2] St Petersburg Acad Univ, RAS, Nanotechnol Res & Educ Ctr, Khlopin Str 8-3, St Petersburg 194021, Russia

[3] Pavlov First St Petersburg State Med Univ, Lva Tolstogo Str 6-8, St Petersburg 197022, Russia

[4] Voeikov Main Geophys Observ, Ul Karbysheva 7, St Petersburg 194021, Russia

来源：

TETRAHEDRON | 2016年 / 72卷 / 33期

基金：

俄罗斯科学基金会;

关键词：

Cyclopropenes; Hydroxylactams; N-Acyliminium cation; Fused-ring systems; Indenes; Lewis acids; DIELS-ALDER REACTIONS; STEREOSELECTIVE-SYNTHESIS; CYCLIZATIONS; DERIVATIVES; CHEMISTRY; ISOXAZOLOPYRROLOISOQUINOLINES; TRANSFORMATIONS; REARRANGEMENT; CONFORMATION; FLUORESCENCE;

D O I：

10.1016/j.tet.2016.06.052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of the reactions of cyclopropenes with N-acyliminium cations is described. 3-(1H-Inden-3-yl)isoindolin-1-ones and cyclopropa[c]isoindolo[2,1-a]quinolones were prepared by BF3 center dot OEt2 mediated reactions of cyclopropenes with the N-acyliminium cations, generated from 2-aryl(benzyl)-3-hydroxyisoindolin-1-ones. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：5064 / 5073

页数：10

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