Formation and structure of [{(CH3)3Si}3C(nC3H7)In(μ-OH)]3

被引：0

作者：

Walz, A ^{[1
]}

Niemeyer, M ^{[1
]}

Weidlein, J ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 04期

关键词：

D O I：

10.1002/(SICI)1521-3749(199904)625:4<547::AID-ZAAC547>3.0.CO;2-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been prepared in low yield by the reaction of [(TKF)(2)LiC(SiMe3)(3)](2) with humid di(n-propyl) indium bromide and purified by sublimation at 110-115 degrees C/10(-3) hPa. This organo indium hydroxe compound forms a trimer via In-OH-In bridges and crystallizes in the triclinic space group P (1) over bar with two trimers and one toluene molecule per unitcell. The In3O3 heterocycle has chair-, the n-propyl ligand has trans-conformation, respectively.

引用

页码：547 / 549

页数：3

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