Initial Investigation into the Leaching of Manganese from Nodules at Room Temperature with the Use of Sulfuric Acid and the Addition of Foundry Slag-Part I

被引:24
|
作者
Toro, Norman [1 ]
Herrera, Nelson [1 ]
Castillo, Jonathan [2 ]
Torres, Cynthia M. [1 ]
Sepulveda, Rossana [2 ]
机构
[1] Univ Catolica Norte, Dept Ingn Met & Minas, Antofagasta 1270709, Chile
[2] Univ Atacama, Dept Ingn Met, Copiapo 1531772, Chile
来源
MINERALS | 2018年 / 8卷 / 12期
关键词
manganese nodules; leaching; secondary mining; slag; DILUTE HCL; INDIAN-OCEAN; DISSOLUTION; PYROLUSITE; REDUCTION; KINETICS; METALS; BEHAVIOR; OXIDES; PYRITE;
D O I
10.3390/min8120565
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
In this study, the surface optimization methodology was used to assess the effect of three independent variables-time, particle size and sulfuric acid concentration-on Mn extraction from marine nodules during leaching with H2SO4 in the presence of foundry slag. The effect of the MnO2/Fe ratio and particle size (MnO2) was also investigated. The maximum Mn extraction rate was obtained when a MnO2 to Fe molar ratio of 0.5, 1 M of H2SO4, -320 + 400 Tyler mesh (-47 + 38 mu m) nodule particle size and a leaching time of 30 min were used.
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页数:13
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