Synthesis of acceptor-doped Ba-Ce-Zr-O perovskites

被引:9
|
作者
Gdula-Kasica, K. [1 ]
Mielewczyk-Gryn, A. [1 ]
Lendze, T. [1 ]
Molin, S. [2 ]
Kusz, B. [1 ]
Gazda, M. [1 ]
机构
[1] Gdansk Univ Technol, Fac Appl Phys & Math, Dept Solid State Phys, Gdansk, Poland
[2] Gdansk Univ Technol, Fac Elect Telecommun & Informat, Dept Biomed Engn, Gdansk, Poland
关键词
molten salt synthesis; intermediate temperature SOFC (IT-SOFC); proton conductivity; OXIDE FUEL-CELLS; GRAIN-GROWTH;
D O I
10.1002/crat.201000380
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In this paper the role of the preparation route on the sintering temperature, microstructure and transport properties of BaCe0.8Y0.1Zr0.1O3-delta solid solution has been studied. In particular, the samples were synthesized by means of the solid-state and molten salt synthesis method. The sample properties were investigated by means of X-ray diffraction, scanning electron microscopy and impedance spectroscopy. It was found that a good sintering of the samples could be achieved at 1500 degrees C for MSS preparation method. The ceramic route, even at higher temperatures, does not lead to better conductivity. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:1251 / 1257
页数:7
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