Alkene Hydroamination via Earth-Abundant Transition Metal (Iron, Cobalt, Copper and Zinc) Catalysis: A Mechanistic Overview

被引：51

作者：

Colonna, Pierre ^{[1
]}

Bezzenine, Sophie ^{[1
]}

Gil, Richard ^{[1
]}

Hannedouche, Jerome ^{[1
]}

机构：

[1] Univ Paris Saclay, Univ Paris Sud, ICMMO, CNRS,UMR 8182, F-91405 Orsay, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 08期

关键词：

alkenes; amines; earth-abundant 3d transition metals; hydroamination; mechanistic studies; CU(I)-CATALYZED INTRAMOLECULAR HYDROAMINATION; H BOND FORMATION; UNACTIVATED ALKENES; ASYMMETRIC HYDROAMINATION; C-N; INTERMOLECULAR HYDROAMINATION; OLEFIN HYDROAMINATION; FORMAL HYDROAMINATION; COMPLEXES; 3-COORDINATE;

D O I：

10.1002/adsc.201901157

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review gives a mechanistic overview of the most relevant advances in the area of alkene (formal) hydroamination promoted by earth-abundant transition metal catalysts involving iron, cobalt, copper and zinc. Focus will be on catalytic systems for which in depth investigations have been conducted to elucidate the activation pathway and operating mechanism. The relevant literature has been covered from 2012 until early 2019.

引用

页码：1550 / 1563

页数：14

共 12 条

[1] Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
Jennifer V. Obligacion
Paul J. Chirik
Nature Reviews Chemistry, 2018, 2 : 15 - 34
[2] Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
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Chirik, Paul J.
NATURE REVIEWS CHEMISTRY, 2018, 2 (05): : 15 - 34
[3] Earth-Abundant 3d Transition Metal Catalysts for Hydroalkoxylation and Hydroamination of Unactivated Alkenes
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Gil, Richard
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CATALYSTS, 2021, 11 (06)
[4] Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis
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[8] Electrochemical reduction of CO2 at the earth-abundant transition metal-oxides/copper interfaces
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CATALYSIS TODAY, 2023, 409 : 53 - 62
[9] Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis
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ORGANIC CHEMISTRY FRONTIERS, 2018, 5 (02): : 260 - 272
[10] Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions
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