Ionic conductivity of NASICON-type LiHf2(PO4)(3): A reexamination

被引：23
|
作者：
MartinezJuarez, A [1 ]
Iglesias, JE [1 ]
Rojo, JM [1 ]
机构：
[1] CSIC,INST CIENCIA MAT,E-28049 MADRID,SPAIN
来源：
SOLID STATE IONICS | 1996年 / 91卷 / 3-4期
关键词：
NASICON; ionic conductivity; lithium hafnium phosphate;
D O I：
10.1016/S0167-2738(96)00450-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ionic conductivity of two pellets of LiHf2(PO4)(3) calcined at 1000 and 1100 degrees C has been measured. Grain interior and grain boundary responses are distinguished in the impedance plots as well as in the real part of conductivity versus frequency plots. The activation energy associated with the motion of Li+ ions inside the grains is 0.33 eV while the activation energy corresponding to the total d.c. conductivity changes from 0.36 to 0.47 eV, depending on the relative contribution of grain interior and grain boundary to that parameter.
引用
收藏
页码：295 / 301
页数：7
相关论文
共 50 条
  • [1] Ionic conductivity of LiHf2(PO4)(3) with NASICON-type structure and its possible application as electrolyte in lithium batteries
    MartinezJuarez, A
    Amarilla, JM
    Iglesias, JE
    Rojo, JM
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 1997, 8 (03) : 261 - 264
  • [2] Phase transition and ionic mobility in LiHf2(PO4)(3) with NASICON structure
    Paris, MA
    MartinezJuarez, A
    Iglesias, JE
    Rojo, JM
    Sanz, J
    CHEMISTRY OF MATERIALS, 1997, 9 (06) : 1430 - 1436
  • [3] Dipole ordering and ionic conductivity in NASICON-Type Na3Cr2(PO4)3 structures
    A. S. Nogai
    S. Yu. Stefanovich
    A. A. Bush
    D. E. Uskenbaev
    A. A. Nogai
    Physics of the Solid State, 2018, 60 : 23 - 30
  • [4] Improved ionic conductivity in NASICON-type Sr2+ doped LiZr2(PO4)3
    Kumar, Sunil
    Balaya, Palani
    SOLID STATE IONICS, 2016, 296 : 1 - 6
  • [5] Dipole Ordering and Ionic Conductivity in NASICON-Type Na3Cr2(PO4)3 Structures
    Nogai, A. S.
    Stefanovich, S. Yu.
    Bush, A. A.
    Uskenbaev, D. E.
    Nogai, A. A.
    PHYSICS OF THE SOLID STATE, 2018, 60 (01) : 23 - 30
  • [6] Structural, electrical conductivity and dielectric relaxation behavior of LiHf2(PO4)3 ceramic powders
    Zangina, Tasiu
    Hassan, Jumiah
    Azis, Raba'ah Syahidah
    Matori, Khamirul Amin
    See, Alex
    Alibe, Ibrahim Mustapha
    Umar, Sadiq
    JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY, 2018, 54 (02) : 307 - 316
  • [7] On processing structure–conductivity relations in NASICON-type LiSn2(PO4)3
    Tanvi Pareek
    Sushmita Dwivedi
    Manish Badole
    Sunil Kumar
    Bulletin of Materials Science, 2021, 44
  • [8] RbSn2(PO4)3, a NASICON-type phosphate
    Zhao, Dan
    Li, FeiFei
    Qiu, Shen
    Jiao, Jiali
    Ren, Junran
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : I32 - U129
  • [9] Ionic conductivity of A3 − 2xNbxAl2 − x(PO4)3 (A = Li, Na) NASICON-type phosphates
    A. R. Shaikhlislamova
    A. Yu. Goryainov
    A. B. Yaroslavtsev
    Inorganic Materials, 2010, 46 : 896 - 899
  • [10] Structural, electrical conductivity and dielectric relaxation behavior of LiHf2(PO4)3 ceramic powders
    Tasiu Zangina
    Jumiah Hassan
    Raba’ah Syahidah Azis
    Khamirul Amin Matori
    Alex See
    Ibrahim Mustapha Alibe
    Sadiq Umar
    Journal of the Australian Ceramic Society, 2018, 54 : 307 - 316
12345