Synthesis of Fluorosugar Reagents for the Construction of Well-Defined Fluoroglycoproteins

被引：17

作者：

Salvado, Miriam ^{[1
]}

Amgarten, Beatrice ^{[2
]}

Castillon, Sergio ^{[1
]}

Bernardes, Goncalo J. L. ^{[2
,3
]}

Boutureira, Omar ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, E-43007 Tarragona, Spain

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[3] Univ Lisbon, Inst Med Mol, Fac Med, P-1649028 Lisbon, Portugal

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 11期

基金：

英国工程与自然科学研究理事会;

关键词：

POSITRON-EMISSION-TOMOGRAPHY; PHASE-TRANSFER CATALYSIS; GLYCOSYL IODIDES; NMR-SPECTRA; PEPTIDES; GLYCOPROTEIN; PROTEINS; PET; BIOCONJUGATION; GLYCOPEPTIDES;

D O I：

10.1021/acs.orglett.5b01259

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Deoxy-2-fluoroglycosyl iodides are privileged glycosyl donors for the stereoselective preparation of 1-Nu-beta-fluorosugars, which are useful reagents for chemical site-selective protein glycosylation. Ready access to such beta-fluorosugars enables the mild and efficient construction of well-defined fluoroglycoproteins.

引用

页码：2836 / 2839

页数：4

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