A pillar[5]arene-calix[4]pyrrole enantioselective receptor for mandelate anion recognition

被引:17
|
作者
Lv, Yongjun [1 ]
Xiao, Chao [2 ,3 ]
Yang, Cheng [2 ,3 ]
机构
[1] Sichuan Univ Sci & Engn, Coll Chem Engn, Mat Corros & Protect Key Lab Sichuan Prov, Zigong 643000, Peoples R China
[2] Sichuan Univ, Coll Chem, State Key Lab Biotherapy, Key Lab Green Chem & Technol,Minist Educ, Chengdu 610064, Sichuan, Peoples R China
[3] Sichuan Univ, Hlth Food Evaluat Res Ctr, Chengdu 610064, Sichuan, Peoples R China
关键词
CHIRAL RECOGNITION; COMPLEXATION;
D O I
10.1039/c8nj04802a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel pillar[5]arene-calix[4]pyrrole macrocyclic compound (PC) featuring anion recognition and host-guest properties was designed and synthesized. This novel macrocycle receptor can be enantioseparated into planar chiral enantiomers that bind R- and S-mandelate guests with an enantioselectivity factor of 2.47.
引用
收藏
页码:19357 / 19359
页数:3
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