3,3′-dimethyl-1,1′-methylenediimidazolium tetrachlorocobaltate(II)

被引：7
|
作者：
Zeller, A
Herdtweck, E
Strassner, T
机构：
[1] Tech Univ Munich, Dept Chem, Lehrstuhl Anorgan Chem, D-85747 Garching, Germany
[2] Tech Univ Dresden, Inst Organ Chem, Lehrstuhl Phys Organ Chem, D-01062 Dresden, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷 / 01期
关键词：
D O I：
10.1107/S0108270104030471
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, (C9H14N4)[CoCl4], a methylene-bridged bis-imidazolium salt containing a tetrachlorocobaltate anion, is one of the first examples where an alkyl-bridged bisimidazolium compound could be structurally characterized. Short C - H ... Cl contacts between the imidazolium C - H bonds and the Cl atoms of the counter-anion build up a three-dimensional network and indicate that the C - H bonds are strongly polarized.
引用
收藏
页码：M46 / M47
页数：2
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