catena-Poly[[[(1,10-phenanthroline-κ2N,N′)manganese(II)]-μ-L-tartrato-κ4O1,O2:O3,O4] hexahydrate]

被引：8
|
作者：
Zhang, XF
Huang, DG
Feng, C
Chen, CN
Liu, QT [1 ]
Sun, LC
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S010827010301761X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, {[Mn(C4H4O6)(C12H8N2)] . 6H(2)O}(n), has a linear chain structure containing monomeric [ Mn( C4H4O6)( C12H8N2)] repeat units. Each manganese ion is six-coordinate, with the two phenanthroline N atoms [Mn - N = 2.229 (2) and 2.235 (2) Angstrom] and four O atoms from two tartrate anions [Mn - O-COO = 2.1252 (19) and 2.1310 (19) Angstrom, and Mn - O-OH = 2.2404 (19) and 2.2424 (19) Angstrom] forming a seriously distorted octahedral coordination environment. Six water molecules exist outside every repeat unit as solvate molecules. Extensive hydrogen-bonding interactions and pi-pi stacking of the phenanthroline moieties exist between the chains.
引用
收藏
页码：M402 / M404
页数：3
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