Dichlorocyclopropane derivatives of syndiotactic 1,2-polybutadiene

被引：5
|
作者：
Glazyrin, A. B. [1 ]
Abdullin, M. I. [1 ]
Muslukhov, R. R. [2 ]
机构：
[1] Bashkir State Univ, Ufa 450014, Bashkortostan, Russia
[2] Russian Acad Sci, Inst Organ Chem, Ufa Res Ctr, Ufa 450054, Bashkortostan, Russia
来源：
POLYMER SCIENCE SERIES B | 2012年 / 54卷 / 3-4期
关键词：
DICHLOROCARBENE; POLYBUTADIENE;
D O I：
10.1134/S1560090412030062
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polymeric products containing hem-dichlorocyclopropane units with a degree of functionalization of up to 97% are synthesized via the reaction of syndiotactic 1,2-polybutadiene with dichlorocarbene obtained by the interaction of chloroform with an aqueous solution of sodium hydroxide in the presence of a phase-transfer catalyst. The incorporation of dichlorocyclopropane groups into units of polydiene substantially changes its molecular mass and polydispersity, the solution viscosity, the polymer melt flowability, and the glass-transition temperature and flow temperature of the polymer.
引用
收藏
页码：234 / 239
页数：6
相关论文
共 50 条
  • [1] Dichlorocyclopropane derivatives of syndiotactic 1,2-polybutadiene
    A. B. Glazyrin
    M. I. Abdullin
    R. R. Muslukhov
    Polymer Science Series B, 2012, 54 : 234 - 239
  • [2] Properties of dichlorocyclopropane derivatives of syndiotactic 1,2-polybutadiene
    Glazyrin, A. B.
    Abdullin, M. I.
    Gazizova, E. R.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2015, 88 (03) : 473 - 479
  • [3] Properties of dichlorocyclopropane derivatives of syndiotactic 1,2-polybutadiene
    A. B. Glazyrin
    M. I. Abdullin
    E. R. Gazizova
    Russian Journal of Applied Chemistry, 2015, 88 : 473 - 479
  • [4] Chlorine derivatives of syndiotactic 1,2-polybutadiene
    M. I. Abdullin
    A. B. Glazyrin
    R. N. Asfandiyarov
    V. R. Akhmetova
    V. N. Zaboristov
    Polymer Science Series B, 2006, 48 : 104 - 107
  • [5] Hydrochlorinated derivatives of syndiotactic 1,2-polybutadiene
    A. B. Glazyrin
    M. I. Abdullin
    R. R. Muslukhov
    V. A. Kraikin
    Polymer Science Series A, 2011, 53 : 110 - 115
  • [6] Formyl derivatives of syndiotactic 1,2-polybutadiene
    Abdullin, MI
    Kukovinets, OS
    Kayumova, MA
    Sigaeva, NN
    Ionova, IA
    Muslukhov, RR
    Zaboristov, VN
    POLYMER SCIENCE SERIES B, 2004, 46 (9-10) : 304 - 307
  • [7] Hydrochlorinated derivatives of syndiotactic 1,2-polybutadiene
    Glazyrin, A. B.
    Abdullin, M. I.
    Muslukhov, R. R.
    Kraikin, V. A.
    POLYMER SCIENCE SERIES A, 2011, 53 (02) : 110 - 115
  • [8] Chlorine derivatives of syndiotactic 1,2-polybutadiene
    Abdullin, M. I.
    Glazyrin, A. B.
    Asfandiyarov, R. N.
    Akhmetova, V. R.
    Zaboristov, V. N.
    POLYMER SCIENCE SERIES B, 2006, 48 (3-4) : 104 - 107
  • [9] Arylamino-derivatives of syndiotactic 1,2-polybutadiene
    Kayumova, M. A.
    Kukovinets, O. S.
    Sigaeva, N. N.
    Muslukhov, R. R.
    Zaboristov, V. N.
    Budtov, V. P.
    Adbullin, M. I.
    POLYMER SCIENCE SERIES B, 2008, 50 (7-8) : 188 - 192
  • [10] Arylamino-derivatives of syndiotactic 1,2-polybutadiene
    M. A. Kayumova
    O. S. Kukovinets
    N. N. Sigaeva
    R. R. Muslukhov
    V. N. Zaboristov
    V. P. Budtov
    M. I. Adbullin
    Polymer Science Series B, 2008, 50 : 188 - 192
12345