Mode-coupling theory predictions for the dynamical transitions of partly pinned fluid systems

被引:38
|
作者
Krakoviack, Vincent [1 ]
机构
[1] Ecole Normale Super Lyon, Chim Lab, F-69364 Lyon 07, France
来源
PHYSICAL REVIEW E | 2011年 / 84卷 / 05期
关键词
ORNSTEIN-ZERNIKE EQUATIONS; GROWING LENGTH SCALES; RANDOM-MEDIA; SLOW DYNAMICS; GLASS; ADSORPTION; RELAXATION; PARTICLES; MOTION;
D O I
10.1103/PhysRevE.84.050501
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The predictions of the mode-coupling theory (MCT) for the dynamical arrest scenarios in a partly pinned (PP) fluid system are reported. The corresponding dynamical phase diagram is found to be very similar to that of a related quenched-annealed (QA) system. The only significant qualitative difference lies in the shape of the diffusion-localization lines at high matrix densities, with a reentry phenomenon for the PP system but not for the QA model, in full agreement with recent computer simulation results. This finding clearly lends support to the predictive power of the MCT for fluid-matrix systems. In addition, the predictions of the MCT are shown to be in stark contrast with those of the random first-order transition theory. The PP systems are thus confirmed as very promising models for differentiating tests of theories of the glass transition.
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页数:5
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