Single-molecule magnet behavior in three cyano-bridged heterometallic FeIII-NiII clusters

被引：27

作者：

Zhuang, Peng-Fei ^{[1
]}

Zhang, Yan-Juan ^{[1
]}

Zheng, Hui ^{[1
]}

Jiao, Cheng-Qi ^{[1
]}

Zhao, Liang ^{[1
]}

Wang, Jun-Li ^{[1
]}

He, Cheng ^{[1
]}

Duan, Chun-Ying ^{[1
]}

Liu, Tao ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 07期

关键词：

CRYSTAL-STRUCTURES; BUILDING-BLOCKS; SPIN; RELAXATION; COMPLEXES; CHAIN; CO; MAGNETIZATION; POLYMERS; SQUARE;

D O I：

10.1039/c4dt03365e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One trinuclear and two tetranuclear cyanide-bridged Fe-III-Ni-II complexes were synthesized via treatment of a tricyanometallate with divalent Ni salts in the presence of 1-butylimidazole, 2,2-bipyrimidyl and 1,10-phenanthroline, respectively. Magnetic property studies demonstrated that the three complexes exhibit single-molecule magnet behavior as a result of strong intracluster ferromagnetic coupling and weak intercluster magnetic interactions.

引用

页码：3393 / 3398

页数：6

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State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian
116024, China
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