One-Step Fabrication of Fluoropolymer Transparent Films with Superhydrophobicity by Dry Method

被引:21
|
作者
Wang, Jian-Ming [1 ]
Wang, Li-Duo [1 ]
Feng, Lin [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
vacuum evaporation; superhydrophobic; superoleophilic; fluoropolymer; SUPER-HYDROPHOBIC SURFACE; ELECTROCHEMICAL DEPOSITION; THIN-FILMS; WETTABILITY; POLYMER; PLASMA;
D O I
10.1002/app.33177
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Fluoropolymer transparent thin films were deposited on different substrates by one-step vacuum evaporation method, which exhibit superhydrophobic property with water contact angle (CA) greater than 150 degrees. Polytetrafluoroethylene (PTFE) film with network structure shows high oleophobicity with oil CA of 138 degrees, whereas polytetrafluoroethylene-perfluoropropylvinylethers (PFA) film with particle structure is superoleophilicity with oil CA near 0 degrees. It is believed that different conformation of -CF2- groups at the surface lead to this different surface activity. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 524-529, 2011
引用
收藏
页码:524 / 529
页数:6
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