Boosting Catalytic Purification of Soot Particles over Double Perovskite-Type La2-xKxNiCoO6 Catalysts with an Ordered Macroporous Structure

The catalytic performances for soot purification over the perovskite-type ABO(3) oxides, as one of the most potential nonnoble metal catalysts, are closely correlated with the substitution of A-site and B-site ions. Herein, three-dimensional ordered macroporous (3DOM) structural catalysts of double perovskite-type La2-xKxNiCoO6 were prepared by a method of colloidal crystal template. The contact efficiency between the catalyst and soot particles is significantly promoted by the 3DOM structure, and the partial substitution of A-site (La) with low-valence potassium (K) ions in La2-xKxNiCoO6 catalysts boosts the increasing surface density of coordinatively unsaturated active B-sites (Co and Ni) and active oxygen. 3DOM La2-xNiCoO6 catalysts exhibited superior performance during the purification of soot particles, and the 3DOM La1.80K0.20NiCoO6 catalyst exhibited the highest activity, that is, the values of T-50, S-CO2, and turnover frequency are 346 degrees C, 99.3%, and 0.204 h(-1) (at 300 degrees C), respectively. According to the results of multiple experimental characterizations and density functional theory calculations, the mechanism of the samples during soot removal is proposed: the increase in surface oxygen density induced by the doping of K ions significantly promotes the critical step of the oxidation from NO to NO2 in catalyzing soot purification. It is one new strategy to develop the high-efficient non-noble metal catalysts for soot purification in practical application.