Reaction of [(COD)RhCl](2) (COD=1,5-cyclooctadiene) with 6,6-dimethyl-fulvene and i-C3H7MgBr: Synthesis, isolation and structural characterization of new pi-complexes of rhodium

被引：0

作者：

Muller, J ^{[1
]}

deOliveira, GNM ^{[1
]}

机构：

[1] UNIV FED SANTA MARIA,DEPT QUIM,BR-97119900 SANTA MARIA,RS,BRAZIL

来源：

QUIMICA NOVA | 1996年 / 19卷 / 06期

关键词：

fulvene-complexes; Rh-pi-complexes; olefin complexes of Rh;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work describes the reaction of [(COD)RhCl](2) (COD = 1,5-Cyclooctadiene) with 6,6-Dimethylfulvene and i-C3H7MgBr. Fractions collected by HPLC-preparative were analysed by mass spectrometry and H-1-NMR, showing the formation of three main groups of complexes: [(Fulvene)Rh(COD)], [(Fulvene)(2)Rh(COD)], and [(Fulvene)(3)Rh(COD)]. The analysis of the isolated complexes has shown that most of them contains ligands formed by fulvene molecules with intermolecular bonds which are novel in the literature.

引用

页码：613 / 619

页数：7

共 15 条

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HAUPT, HJ
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[4] Synthesis of the complexes [PdCIR(cod)] (R equals benzyl, ethyl; cod equals 1,5-cyclooctadiene). beta-elimination from [PdClEt(cod)] to give the eta(1),eta(2), and eta(3) isomers of [Pd-2(mu-Cl)(2)(C8H13)(2)]
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[5] STRUCTURES OF 2 6,6-DIARYLFULVENE COMPLEXES OF RHODIUM - (1,5-CYCLOOCTADIENE)-(6,6-DIPHENYLFULVENE)RHODIUM(I) PERCHLORATE, [RH(C8H12)(C18H14)]CLO4, (I), AND [6,6-BIS(4-CHLOROPHENYL)FULVENE]BIS(TRIPHENYL PHOSPHITE) RHODIUM(I) PERCHLORATE, [RH(C18H12CL2)(C18H15O3P)2]CLO4,(II)
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ORGANOMETALLICS, 1993, 12 (05) : 1523 - 1536

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