Metal-organic framework ZIF-8 loaded with rhodium nanoparticles as a catalyst for hydroformylation

被引：6
|
作者：
Vlasenko, Ekaterina S. [1 ,2 ]
Nikovskiy, Igor A. [1 ]
V. Nelyubina, Yulia [1 ]
Korlyukov, Alexander A. [1 ]
V. Novikov, Valentin [1 ,2 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[2] Natl Res Univ Higher Sch Econ, Moscow 101000, Russia
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
hydroformylation; metal-organic frameworks; reaction vessel; catalyst; rhodium nanoparticles; MOFS;
D O I：
10.1016/j.mencom.2022.05.009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Porous metal-organic framework ZIF-8 materials containing incorporated rhodium (Rh@ZIF-8) and rhodium chloride (RhCl3@ZIF-8) nanoparticles were obtained and tested as a catalytic reaction vessel in the reactions of hydroformylation of 1-decene and styrene. Catalytic tests with Rh@ZIF-8 showed that the selectivity and conversion of the hydroformylation reaction depended on the size of the substrate molecule. The incorporation of catalytic nanoparticles into the pores of a metal-organic framework opens up new possibilities for regioselective hydroformylation.
引用
收藏
页码：320 / 322
页数：3
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