Comparing the Efficiency of N-Doped TiO2 and N-Doped Bi2MoO6 Photo Catalysts for MB and Lignin Photodegradation

被引:25
|
作者
Rangel, Ricardo [1 ]
Janneth Cedeno, Veronica [1 ]
Espino, Jaime [1 ]
Bartolo-Perez, Pascual [2 ]
Rodriguez-Gattorno, Geonel [2 ]
Jose Alvarado-Gil, Juan [2 ]
机构
[1] Univ Michoacana SNH, Fac Ingn Quim, Div Estudios Posgrad, Morelia 58060, Michoacan, Mexico
[2] IPN, CINVESTAV, Unidad Merida, Merida 97310, Yucatan, Venezuela
来源
CATALYSTS | 2018年 / 8卷 / 12期
关键词
photocatalysis; Titanium dioxide; bismuth molybdate; lignin; UV light; visible light; VISIBLE-LIGHT PHOTOCATALYSIS; NANOPARTICLES;
D O I
10.3390/catal8120668
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, we tested the efficiency of nitrogen-doped titanium dioxide (N-TiO2) and nitrogen-doped bismuth molybdate (N-Bi2MoO6) compounds as photocatalysts capable of degrading methylene blue and lignin molecules under irradiation with ultraviolet (UV) and visible light (VIS). Moreover, we compared TiO2 and Bi2MoO6 catalysts with N-TiO2 and N-Bi2MoO6 compounds using chemical coprecipitation. The catalysts were prepared starting from Ti(OCH2CH2CH3)(4), Bi(NO3)(3)center dot 5H(2)O, and (NH4)(6)Mo7O24 reagents. N-doping was achieved in a continuous reflux system, using ethylene diamine as a nitrogen source. The resulting materials were characterized using Scanning Electron Microscopy (SEM), X-Ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Additionally, we observed the decrease in particle size after processing the compounds in the reflux system. The results regarding photocatalytic degradation tests show a remarkable effect for nitrogen doped samples, achieving 90% of lignin degradation.
引用
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页数:12
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