The product of a regiospecific and stereoselective ene-reaction of a polycyclic terpenoid system

被引:0
|
作者
Abad, A
Agulló, C
Cuñat, AC
Navarro, I
de Arellano, CR [1 ]
机构
[1] Univ Valencia, Fac Farm, Dept Quim Organ, Valencia 46100, Spain
[2] Univ Valencia, Fac Quim, Dept Quim Organ, Valencia 46100, Spain
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词
D O I
10.1107/S1600536801008510
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The X-ray structure of dimethyl (Z)-[(8aS,2R,4aR,4bR)-8a-methoxycarbonyl-1,4a,7-trimethyl-8-oxo-2,3,4,4a,4b,5,8,8a,9,- 10-decahydrophenanthren-2-yl]-2-butenedioate, C25H32O7, confirmed its relative configuration. The structure shows the bend in the molecular skeleton as found for similar compounds. Weak intermolecular C-H . . .O interactions have been found in the crystal.
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页码:o553 / o554
页数:2
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