Extraction of Lanthanide Nitrates in Multicomponent Aqueous-Organic Two-Phase Systems with D2EHPA

被引：6

作者：

Belova, V. V. ^{[1
]}

Martynova, M. M. ^{[1
]}

Erastov, A. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

lanthanide nitrates; di(2-ethylhexyl) phosphoric acid; multicomponent aqueous-organic biphasic systems; interphase distribution; separation; COUNTER-CURRENT CHROMATOGRAPHY; LIQUID-LIQUID CHROMATOGRAPHY; CENTRIFUGAL PARTITION CHROMATOGRAPHY; PHOSPHORIC-ACID; SAMPLE INJECTION; STEADY-STATE; SEPARATION; MODE; MIXTURE; CELL;

D O I：

10.1134/S0036023618120033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lanthanum nitrate distribution in three-component aqueous-organic systems with D2EHPA from acetate or acetic acid-acetate solutions has been studied, it has been shown that variation in sodium acetate concentration or composition of CH3COONa-CH3COOH mixture can affect metal distribution ratios. It has been found that extraction in three-component mixture of 1: 1: 1 composition (aqueous solution Ln(NO3)(3) + CH3COONa + CH3COOH-D2EHPA in hexane-isopropyl alcohol) can provide lanthanide separation, which is dependent on the ratio of sodium acetate and acetic acid in aqueous phase and on D2EHPA concentration in organic phase. Lanthanide-lanthanum separation factors have been calculated for the extraction of lanthanide nitrates from acetic acid-acetate solutions.

引用

页码：1651 / 1655

页数：5

共 50 条

[1] Extraction of Lanthanide Nitrates in Multicomponent Aqueous-Organic Two-Phase Systems with D2EHPA
V. V. Belova
M. M. Martynova
A. A. Erastov
Russian Journal of Inorganic Chemistry, 2018, 63 : 1651 - 1655
[2] Interphase Distribution of Lanthanide Salts in Multicomponent Aqueous-Organic Two-Phase Systems
Belova, V. V.
Martynova, M. M.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2019, 53 (05) : 921 - 924
[3] Interphase Distribution of Lanthanide Chlorides in Multicomponent Aqueous-Organic Two-Phase Systems Containing DEHPA
Belova, V. V.
Martynova, M. M.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2020, 54 (04) : 775 - 780
[4] EXTRACTION OF METAL-IONS WITH D2EHPA FROM MIXED AQUEOUS-ORGANIC MEDIA
KAMITANI, M
SHIBATA, J
SANO, M
NISHIMURA, S
SOLVENT EXTRACTION AND ION EXCHANGE, 1988, 6 (04) : 605 - 619
[5] Extraction of Lanthanide Chlorides in Aqueous-Organic Two-Phase Systems with Salts of Tertiary and Secondary Amines
V. V. Belova
Yu. V. Tsareva
Theoretical Foundations of Chemical Engineering, 2020, 54 : 1096 - 1101
[6] Extraction of Lanthanide Chlorides in Aqueous-Organic Two-Phase Systems with Salts of Tertiary and Secondary Amines
Belova, V. V.
Tsareva, Yu. V.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2020, 54 (05) : 1096 - 1101
[7] Interphase Distribution of Lanthanide Salts in Multicomponent Aqueous–Organic Two-Phase Systems
V. V. Belova
M. M. Martynova
Theoretical Foundations of Chemical Engineering, 2019, 53 : 921 - 924
[8] Interphase Distribution of Lanthanide Nitrates in Aqueous Organic Two-Phase Systems with Amine and Organic Acid Salts
Belova, V. V.
Tsareva, Yu. V.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2020, 54 (04) : 769 - 774
[9] Interphase Distribution of Lanthanide Nitrates in Aqueous Organic Two-Phase Systems with Amine and Organic Acid Salts
V. V. Belova
Yu. V. Tsareva
Theoretical Foundations of Chemical Engineering, 2020, 54 : 769 - 774
[10] Interphase Distribution of Lanthanide Chlorides in Multicomponent Aqueous–Organic Two-Phase Systems Containing DEHPA
V. V. Belova
M. M. Martynova
Theoretical Foundations of Chemical Engineering, 2020, 54 : 775 - 780

← 1 2 3 4 5 →