Tricritical Phenomena and Cascades of Temperature Phase Transitions in a Ferromagnetic Liquid Crystal Suspension

被引:1
|
作者
Khalilov, Timur [1 ]
Makarov, Dmitriy [1 ]
Petrov, Danil [1 ]
机构
[1] Perm State Univ, Phys Phase Transit Dept, Perm 614990, Russia
来源
CRYSTALS | 2021年 / 11卷 / 06期
基金
俄罗斯基础研究基金会;
关键词
Landau-de Gennes theory; ferromagnetic nematic; phase transition; triple point; tricritical point; FERRONEMATICS; MORPHOLOGIES; ORDER;
D O I
10.3390/cryst11060639
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We consider temperature-driven phase transitions occurring in a liquid crystal suspension of ferromagnetic particles within the Landau-de Gennes theory. The temperature dependences of the order parameters in the uniaxial model with a vector order parameter for the magnetic subsystem are obtained. The dimensionless expression for the free energy density of the suspension has been used for the study of the phase behavior general regularities of the system. Phase state diagrams of the suspension and temperature dependences of the order parameters of the liquid crystal and the ensemble of magnetic particles for different values of the phenomenological expansion coefficients are constructed. It is shown that the considered model admits the existence of a cascade of temperature phase transitions: isotropic phase-superparamagnetic nematic phase-ferromagnetic nematic phase. We have shown that in the mesomorphic state of the liquid crystal, the spontaneous magnetization can appear in a continuous way or by a jump with decreasing temperature, which corresponds to the tricritical behavior. The values of temperature and expansion coefficients corresponding to the tricritical and triple points are numerically found.
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页数:12
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