Processing of inorganic-organic hybrids from metal alkoxides and phenyltriethoxysilane

被引:2
|
作者
Yoshinaga, I [1 ]
Yamada, N [1 ]
Katayama, S [1 ]
机构
[1] Nippon Steel Corp Ltd, Adv Technol Res Labs, Nakahara Ku, Kawasaki, Kanagawa 2110035, Japan
来源
关键词
D O I
10.1557/PROC-519-285
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the synthesis of inorganic-organic hybrids from metal alkoxides and phenyltriethoxysilane (PTES), metal alkoxides were found to influence the phenyl siloxane network formation. The presence of metal alkoxides in the initial stage of hydrolysis and condensation of PTES promote the formation of phenyl siloxane networks to provide a dense hybrid. However, the presence of metal alkoxides in the stage of hydrolyzed PTES provide a loose structure of phenyl siloxane networks involving a number of silanol groups.
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页码:285 / 290
页数:6
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