Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes

被引：820
|
作者：
Yun, Qinbai [1 ,2 ]
He, Yan-Bing [1 ]
Lv, Wei [1 ]
Zhao, Yan [1 ,2 ]
Li, Baohua [1 ]
Kang, Feiyu [1 ,2 ]
Yang, Quan-Hong [1 ,3 ]
机构：
[1] Tsinghua Univ, Grad Sch Shenzhen, Shenzhen Key Lab Graphene Based Mat & Engn, Lab Functionalized Carbon Mat, Shenzhen 518055, Peoples R China
[2] Tsinghua Univ, Sch Mat Sci & Engn, Adv Mat Lab, Beijing 100084, Peoples R China
[3] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源：
ADVANCED MATERIALS | 2016年 / 28卷 / 32期
基金：
中国国家自然科学基金;
关键词：
LITHIUM-METAL; HIGH-ENERGY; ELECTROLYTES; BATTERIES; DEPOSITION; LAYER; POLYSULFIDE; DENSITY; GROWTH;
D O I：
10.1002/adma.201601409
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 3D porous Cu current collector is fabricated through chemical dealloying from a commerial Cu-Zn alloy tape. The interlinked porous framework naturally integrated can accommodate Li deposition, suppressing dendrite growth and alleviating the huge volume change during cycling. The Li metal anode combined with such a porous Cu collector demonstrates excellent performance and commerial potentials in Li-based secondary batteries.
引用
收藏
页码：6932 / +
页数：9
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