Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ2N2,N2′)copper(II)

被引:1
|
作者
El Ghayati, Lhoussaine [1 ]
El Ammari, Lahcen [2 ]
Taha, Mohamed Labd [3 ]
Tjiou, El Mostafa [1 ]
机构
[1] Univ Mohammed V Agdal, Fac Sci, Lab Chim Organ Heterocycl, Rabat, Morocco
[2] Univ Mohammed V Agdal, Fac Sci, Lab Chim Solide Appl, Rabat, Morocco
[3] Univ Ibn Zohr, Fac Sci, Lab Chim Bio Organ Appl, Agadir, Morocco
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
PYRAZOLES;
D O I
10.1107/S1600536811004375
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [CuCl2(C9H12N4)], the Cu-II atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu-II atom is essentially planar, with a maximum deviation of 0.0181 (17) angstrom for one of the coordinated N atoms. This plane forms a dihedral angle of 30.75 (6)degrees with the CuCl2 plane. In the crystal, each pair of adjacent molecules is linked into a centrosymmetric dimer by N-H center dot center dot center dot Cl hydrogen bonds. The crystal structure is stabilized by intermolecular C-H center dot center dot center dot N and C-H center dot center dot center dot Cl hydrogen bonds and weak slipped pi-pi stacking interactions between symmetry-related molecules, with an interplanar separation of 3.439 (19) angstrom and a centroid-centroid distance of 3.581 (19) angstrom.
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页码:M323 / U393
页数:10
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