Heterogeneous Iron-Catalyzed Hydrogenation of Nitroarenes under Water-Gas Shift Reaction Conditions

被引：5
|
作者：
Ryabchuk, Pavel [1 ]
Junge, Kathrin [1 ]
Beller, Matthias [1 ]
机构：
[1] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
SYNTHESIS-STUTTGART | 2018年 / 50卷 / 22期
基金：
欧洲研究理事会;
关键词：
reduction; water-gas shift reaction; WGSR; heterogeneous catalysis; iron; nanoparticles; nitroarenes; hydrogenation; CHEMOSELECTIVE REDUCTION; NUCLEOPHILIC ALLYLATION; NITRO-COMPOUNDS; CO; H2O; COMPLEXES; DRIVEN; GOLD;
D O I：
10.1055/s-0037-1610196
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reduction of various nitroarenes in the presence of heterogeneous iron oxide-based catalyst Fe2O3/NGr@ C under water-gas shift reaction (WGSR) conditions has been demonstrated. The catalytic material is prepared in a straightforward manner via deposition/pyrolysis of iron-phenanthroline complex on carbon support. It shows high chemoselectivity towards the reduction of nitroarenes in the presence of other reducible and/or poisoning-capable functional groups. Hydrogenation is achieved using CO/H2O as a hydrogen source. Furthermore, it is demonstrated that the presence of triethylamine additive has a significant positive effect on the rate of reduction.
引用
收藏
页码：4369 / 4376
页数：8
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