Synthesis of metalloporphyrins by microwave irradiation and their fluorescent properties

被引：13
|
作者：
Liu, MO
Tai, CH
Hu, AT [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30043, Taiwan
[2] Ind Technol Res Inst, Union Chem Labs, Hsinchu 300, Taiwan
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2005年 / 92卷 / 2-3期
关键词：
porphyrin; metalloporphyrin; microwave; fluorescent; heavy-atom effect;
D O I：
10.1016/j.matchemphys.2004.09.027
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Soluble 5,10,15,20-tetrakis(4-tert-butylphenyl) metalloporphyrins [M(TBP), M = Mg, Cu, Tb(OAc), Lu(OAc), La(OAc)] have been rapidly synthesized by microwave irradiation. They can be prepared from 5,10,15,20-tetrakis(4-tert-butylphenyl) porphyrins [H-2(TBP)] or from pyrrole and 4-tert-butylbenzaldehyde with appropriate metal salts. Furthermore, their fluorescent properties have also been investigated. The experimental results reveal that the fluorescent properties of metalloporphyrins depend on their central metals due to heavy-atom effect. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：322 / 326
页数：5
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