On a general system-partitioning in the many-electron correlation problem

被引：0

作者：

Mukhopadhyay, A

机构：

[1] Saha Institute of Nuclear Physics, 1/AF Bidhannagar

来源：

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY | 1996年 / 60卷 / 01期

关键词：

D O I：

10.1002/(SICI)1097-461X(1996)60:1<261::AID-QUA27>3.0.CO;2-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

General system partitioning in the many-electron correlation problem for atomic and molecular systems is addressed within the spinshift formalism. The conventional method of the unitary group subduction coefficient expansion is reconsidered in the latter framework and an orbital-level factorization of the coefficients is obtained. ''Group-spinshifts'' are introduced and exploited to propose an alternative method of generating states adapted to arbitrary subduction chains. (C) 1996 John Wiley & Sons, Inc.

引用

页码：261 / 271

页数：11

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